Molecular addition compounds. 15. Synthesis, hydroboration, and reduction studies of new, highly reactive tert-butyldialkylamine-borane adducts

…, JVB Kanth, PV Dalvi, M Zaidlewicz

Index: Brown, Herbert C.; Kanth, Josyula V. B.; Dalvi, Pramod V.; Zaidlewicz, Marek Journal of Organic Chemistry, 1999 , vol. 64, # 17 p. 6263 - 6274

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Citation Number: 69

Abstract

Two series of tert-butyldialkylamines have been prepared and examined for borane complexation. The complexing ability of each amine in the two series examined decreases in the order shown. First series: t-BuN (CH2CH2) 2O 1a> t-BuNEt2 1b> t-BuNPr n 2 1c> t- BuN (CH2CH2OMe) 2 1d≫ t-BuNBu i 2 1e. Second series: t-BuNBu i Me 2a> t-BuNPr i Me 2b> t-BuNBu i Et 2c> t-BuNBu i Prn 2d≫ t-BuNPr i Et 2e. The reactivity of the ...