Tetrahedron

An efficient and stereoselective synthesis of insect pheromones by way of nickel-catalyzed Grignard reactions. Syntheses of gossyplure and pheromones of Eudia …

JP Ducoux, P Le Ménez, N Kunesch, G Kunesch…

Index: Ducoux, Jean-Philippe; Le Menez, Patrick; Kunesch, Nicole; Kunesch, Gerhard; Wenkert, Ernest Tetrahedron, 1992 , vol. 48, # 31 p. 6403 - 6412

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Citation Number: 15

Abstract

Three pheromones,(6Z, 11Z)-hexadeca-6, 11-dien-1-yl acetate (from Eudia pavonia),(5Z, 9Z)-heptacosa-5, 9-diene (from Drosophila melanogaster) and gossyplure, have been synthesized each by two consecutive consequences of nickel-assisted Grignard reactions with cyclic enol ethers and preparation of Grignard reagents from the resultant alcohols.

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