Metalations of Diphenylmethane and Related Compounds by Potassium Amide. Condensations with Carbonyl Compounds1
RS Yost, CR Hauser
Index: Yost; Hauser Journal of the American Chemical Society, 1947 , vol. 69, p. 2325,2327
Full Text: HTML
Citation Number: 11
Abstract
Although certain condensations have been effected fairly satisfactorily in this medium, the diphenylmethane is probably not completely metalated since this hydrocarbon appears to be only a slightly stronger acid than amm~ nia.~ However, essentially complete metalation has been realized by driving off the ammonia leaving the diphenylmethylpotassium suspended in ether. 4 Carbonation of the ether suspension with excess Dry Ice has given ...
Related Articles:
[Kunishima, Munetaka; Kawachi, Chiho; Morita, Jun; Terao, Keiji; Iwasaki, Fumiaki; Tani, Shohei Tetrahedron, 1999 , vol. 55, # 46 p. 13159 - 13170]
Rhodium Catalyzed Arylation of Diazo Compounds with Aryl Boronic Acids
[Kothapalli, Raveendra Babu; Niddana, Ramana; Balamurugan, Rengarajan Organic Letters, 2014 , vol. 16, # 5 p. 1278 - 1281]
Palladium/Copper??Catalyzed Di?螃窿?arylation of Acetic Acid Esters
[Song, Bingrui; Himmler, Thomas; Goossen, Lukas J. Advanced Synthesis and Catalysis, 2011 , vol. 353, # 10 p. 1688 - 1694]
Samarium Diiodide as an Efficient Catalyst for the Conversion of N-Acyloxazolidinones into Esters
[Magnier-Bouvier, Caroline; Reboule, Irena; Gil, Richard; Collin, Jacqueline Synlett, 2008 , # 8 p. 1211 - 1215]
Palladium/Copper??Catalyzed Di?螃窿?arylation of Acetic Acid Esters
[Song, Bingrui; Himmler, Thomas; Goossen, Lukas J. Advanced Synthesis and Catalysis, 2011 , vol. 353, # 10 p. 1688 - 1694]