Tetrahedron

Reduktive fragmentierung—III: Solvatationseffekte bei der reduktion von bicyclo [2.2. 2] octyltosylaten mit lithiumaluminiumhydrid

W Kraus, C Chassin, R Chassin

Index: Kraus,W. et al. Tetrahedron, 1969 , vol. 25, p. 3681 - 3692

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Citation Number: 11

Abstract

The reduction of 1-methyl-4-tosyloxy-bicyclo [2.2. 2] octan-2-one (2) with LAH proceeds by fragmentation to 1-methyl-4-hydroxymethyl-4-methylene-cyclohexane (4) without any influence of the solvent on the product composition. On the other hand the course for the ...