Capturing a Ghost. Synthesis and Structural Characterization of Pd (dba)[P (o-Tol) 3] 2

…, W Dougherty Jr, S Kassel, FE Goodson

Index: Harding, Brennen A.; Melvin, Patrick R.; Dougherty, William; Kassel, Scott; Goodson, Felix E. Organometallics, 2013 , vol. 32, # 12 p. 3570 - 3573

Full Text: HTML

Citation Number: 8

Abstract

In an effort to improve upon a literature synthesis of bis [tris (o-tolyl) phosphine] palladium (0)(1) from tris (o-tolyl) phosphine and Pd2 (dba) 3, we instead isolated a new compound which proved to have the composition Pd (dba)[P (o-Tol) 3] 2 (2), upon analysis by X-ray crystallography. While this is not the first known palladium compound containing both dba and phosphine ligands, it is, to our knowledge, the first containing dba and tris (o-tolyl) ...

Related Articles:

1, 6-Diene Complexes of Palladium (0) and Platinum (0): Highly reactive sources for the naked metals and [L-M0] Fragments

[Krause, Jochen; Cestaric, Guenter; Haack, Karl-Josef; Seevogel, Klaus; Storm, Werner; Poerschke, Klaus-Richard Journal of the American Chemical Society, 1999 , vol. 121, # 42 p. 9807 - 9823]

Palladium-catalyzed formation of carbon-nitrogen bonds. Reaction intermediates and catalyst improvements in the hetero cross-coupling of aryl halides and tin …

[Paul, Frederic; Patt, Joe; Hartwig, John F. Journal of the American Chemical Society, 1994 , vol. 116, # 13 p. 5969 - 5970]

A Route to Pdo from PdII Metallacycles in Animation and Cross??Coupling Chemistry

[Angewandte Chemie - International Edition in English, , vol. 35, # 20 p. 2359 - 2361]

A Route to Pdo from PdII Metallacycles in Animation and Cross??Coupling Chemistry

[Angewandte Chemie - International Edition in English, , vol. 35, # 20 p. 2359 - 2361]

More Articles...