The [Cu]-catalyzed SN AR reactions: direct amination of electron deficient aryl halides with sodium azide and the synthesis of arylthioethers under Cu (II)–ascorbate …

Y Goriya, CV Ramana

Index: Goriya, Yogesh; Ramana Tetrahedron, 2010 , vol. 66, # 38 p. 7642 - 7650

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Citation Number: 38

Abstract

A one pot [Cu]-promoted SNAr reaction of electron-deficient halobenzenes with sodium azide and the reduction of the intermediate aryl azides under the same Cu (II)–ascorbate redox conditions leading to anilines has been documented. Control experiments revealed