Australian Journal of Chemistry

… Reaction of Some N-(Nitrophenyl) azoles With Alkali: Preparation of the Corresponding Azoxybenzenes. X-Ray Structure of 2, 2′-Bis (1 ″, 2 ″, 4 ″-triazol-1 ″-yl) …

MF Mackay, GJ Trantino, JFK Wilshire

Index: Mackay, Maureen F.; Trantino, Giuseppe J.; Wilshire, John F. K. Australian Journal of Chemistry, 1993 , vol. 46, # 4 p. 417 - 425

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Citation Number: 5

Abstract

Abstract The reactions of some representative N-(nitrophenyl) azoles with boiling aqueous ethanolic potassium hydroxide solution gave the corresponding bis (azolyl) azoxybenzenes. It is deduced that, in these reactions, the N-attached azolyl groups concerned are acting as weak electron-withdrawing groups. The structure of 2, 2′-bis (1 ″, 2 ″, 4 ″-triazol-1 ″-yl) azoxybenzene was determined in the solid state by X-ray crystallography. The monoclinic ...