Sulfides as precursors for sulfonyl chloride synthesis

RF Langler, ZA Marini…

Index: Langler,R.F. et al. Canadian Journal of Chemistry, 1979 , vol. 57, p. 3193 - 3199

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Citation Number: 16

Abstract

Sulfides are advanced as sulfonyl chloride precursors. SN2 cleavage of the intermediate sulfonium ions is discussed in conjunction with both the sulfohaloform pathway and our previous hypothesis that asymmetric chlorosulfonium chloride salts undergo Pummerer rearrangements which exhibit regioselectivity that can be anticipated on the basis of substituent electronegativity difference (Δ X p). Thioglycolic acid is developed as a new ...

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