Journal of fluorine chemistry

Synthesis and thiolation of 1, 3-difluoro-2, 4, 6-trihaloanilines and benzenes

JT Manka, P Kaszynski

Index: Manka, Jason T.; Kaszynski, Piotr Journal of Fluorine Chemistry, 2003 , vol. 124, # 1 p. 39 - 43

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Citation Number: 4

Abstract

Three pentahaloanilines were prepared by stepwise halogenation of 3, 5-difluoroaniline and were deaminated to form pentahalobenzenes. Alternatively, two pentahalobenzenes were obtained by lithiation followed by iodination of 1, 3-difluoro-4, 6-dihalobenzenes. Alkylthiolation reactions of pentahaloanilines and benzenes in Me2SO were investigated.