Liebigs Annalen der Chemie

A method for the simultaneous preparation of alkyl isothiocyanates and thiols

G Błotny

Index: Blotny, Grzegorz Liebigs Annalen der Chemie, 1982 , # 10 p. 1927 - 1932

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Citation Number: 9

Abstract

We have found in a previous study that ethyl dithiocarbamates 2 derived from primary amines undergo pyrolysis in the injection port of a gas chromatograph to yield isothiocyanates 3 and ethanethiole (Scheme l), whereas derivatives of secondary amines do not. On this basis we devel-

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