Rhodium (III)??Catalyzed Dehydrogenative Heck Reaction of Salicylaldehydes

Z Shi, N Schröder, F Glorius

Index: Shi, Zhuangzhi; Schroeder, Nils; Glorius, Frank Angewandte Chemie - International Edition, 2012 , vol. 51, # 32 p. 8092 - 8096

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Citation Number: 86

Abstract

The transition-metal-catalyzed Mizoroki–Heck reaction is one of the most popular and powerful tools for CÀC bond formation and offers a straightforward approach for the construction of olefination products.[1] Three kinds of substrates are typically utilized as the coupling partner for the olefin in this reaction: aryl halides or pseudohalides, organometallic reagents, and non-preactivated (hetero) arenes. In terms of atom economy the third type of ...

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