Novel Support Effects on the Mechanism of Propene-Deuterium Addition and Exchange Reactions over Dispersed ZrO 2
S Naito, M Tanimoto
Index: Naito, Shuichi; Tanimoto, Mitsutoshi Journal of Catalysis, 1995 , vol. 154, # 2 p. 306 - 313
Full Text: HTML
Citation Number: 18
Abstract
The effect on the rate and mechanisms of propene-deuterium reactions of dispersing ZrO2 on various supports such as silica, alumina, and titanium dioxide has been studied by microwave spectroscopic analysis of monodeuteropropene as well as by kinetic investigation. By dispersal of ZrO2 on these supports, the rate of the C3H6-D2 reactions is increased considerbly compared to that over unsupported ZrO2, with the decrease of ...
Related Articles:
[Naito, Shuichi; Tanimoto, Mitsutoshi Journal of the Chemical Society, Chemical Communications, 1987 , # 5 p. 363 - 365]
Protonation of C3H6 isomers: isotope exchange and isomerization
[Hunter, Edward P.; Lias, S. G. Journal of Physical Chemistry, 1982 , vol. 86, # 14 p. 2769 - 2775]
[John, Christopher S.; Williamson, James G.; Kennedy, Lois V. F.; Tyler, J. Kelvin Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1980 , vol. 76, p. 1356 - 1365]
Carbon acidity. 58. Hydrogen isotope exchange kinetics of propylene with lithium cyclohexylamide
[Boerth, Donald W.; Streitwieser, Andrew Jr. Journal of the American Chemical Society, 1981 , vol. 103, # 21 p. 6443 - 6447]
Mechanism of the Decomposition of Silacyclobutane to Silylene and Propene
[Barton,T.J.; Tillman,N. Journal of the American Chemical Society, 1987 , vol. 109, p. 6711]