Cobalt (II)??Catalyzed 1, 4??Addition of Organoboronic Acids to Activated Alkenes: An Application to Highly cis??Stereoselective Synthesis of Aminoindane Carboxylic …

…, S Mannathan, PS Lin, CH Cheng

Index: Chen, Min-Hsien; Mannathan, Subramaniyan; Lin, Pao-Shun; Cheng, Chien-Hong Chemistry - A European Journal, 2012 , vol. 18, # 47 p. 14918 - 14922

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Abstract

Transition-metal-catalyzed 1, 4-addition of organometallic reagents to activated alkenes is a useful method for the efficient construction of carbon–carbon bonds in organic synthesis.[1] A wide range of organometallic reagents has been commonly employed for this reaction.[2– 6] Among these, organoboron reagents exhibit a multifarious advantage, comprising safe handling, availability, and stability to air and moisture.[7] In this context, the rhodium-[8] ...

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