Tetrahedron Letters

Hydrosilylation of tetrasubstituted olefins

K Oertle, H Wetter

Index: Oertle, Konrad; Wetter, Hansjuerg Tetrahedron Letters, 1985 , vol. 26, # 45 p. 5511 - 5514

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Citation Number: 48

Abstract

Abstract Tetrasubstituted olefins are hydrosilylated under very mild conditions with dimethyl- or butylmethylchlorosilane and aluminium chloride as catalyst. Application of this procedure to 2, 3-dimethyl-2-butene yields thexyldimethylsilyl chloride, a new silicon based protective group reagent.