REACTIONS IN THE CHLOROSILANE-SILANOL-SILOXANE SYSTEM
K Rühlmann
Index: Ruehlmann, K. Phosphorus and Sulfur and the Related Elements, 1986 , vol. 27, p. 139 - 152
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Citation Number: 2
Abstract
Abstract We obtained the first σ∗-values and Es-values for siloxy groups by spectroscopic and kinetic methods. Detailed mechanistic investigations are performed on the hydrolysis of chlorosiloxanes, the cleavage of Si [sbnd] O [sbnd] Si bonds by HCl, and the substituent exchange reaction between silanols and chlorosilanes.
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