General methodology for the synthesis of conjugated dienic insect sex pheromones
M Gardette, N Jabri, A Alexakis, JF Normant
Index: Gardette, M.; Jabri, A.; Alexakis, A.; Normant, J. F. Tetrahedron, 1984 , vol. 40, # 14 p. 2741 - 2750
Full Text: HTML
Citation Number: 57
Abstract
A general methodology for the synthesis of various types of dienic insect sex pheromones (ZE, EZ, ZZ) is based on the carbocupration of acetylene by functionalised or non- functionalised lithium dialkyl cuprates, followed by the coupling of the resulting Z dialkenyl cuprates with functionalised or non-functionalised E or Z alkenyl iodides under Pd° catalysis. The following compounds were efficiently synthesized with a high degree of ...
Related Articles:
[Cassani, G.; Massardo, P.; Piccardi, P. Tetrahedron Letters, 1983 , vol. 24, # 24 p. 2513 - 2516]
[Descoins,C. et al. Bulletin de la Societe Chimique de France, 1977 , p. 941 - 946]
Stereoselective Syntheses of (E)-7,(Z)-9 Dodecadien-1-Yl Acetate
[Descoins, C.; Lettere, M.; Linsrumelle, G.; Michelot, D.; Ratovelomanana, V. Synthetic Communications, 1984 , vol. 14, # 8 p. 761 - 774]
Synthesis of (7E, 9Z)-7, 9-dodecadien-1-yl acetate, a sex pheromone of Lobesia botrana
[Labovitz,J.N. et al. Tetrahedron Letters, 1975 , p. 4209 - 4212]
[Descoins,C. et al. Bulletin de la Societe Chimique de France, 1977 , p. 941 - 946]