Tetrahedron Letters

Iron-catalyzed conversion of unactivated aryl halides to phenols in water

Y Ren, L Cheng, X Tian, S Zhao, J Wang, C Hou

Index: Ren, Yunlai; Cheng, Lin; Tian, Xinzhe; Zhao, Shuang; Wang, Jianji; Hou, Chaodong Tetrahedron Letters, 2010 , vol. 51, # 1 p. 43 - 45

Full Text: HTML

Citation Number: 17

Abstract

Although iron is low-cost and environmentally friendly, there is no report about iron- catalyzed conversion of unactivated aryl halides to phenols. In this Letter, a new method for the present conversion was developed with iron compounds as the catalyst and water as the solvent. The suggested method allowed a series of unactivated aryl bromides and aryl iodides to be converted into the corresponding substituted phenols in moderate to high ...

Related Articles:

Simple and efficient CuI/PEG-400 system for hydroxylation of aryl halides with potassium hydroxide

[Chen, Junmin; Yuan, Tangjun; Hao, Wenyan; Cai, Mingzhong Catalysis Communications, 2011 , vol. 12, # 15 p. 1463 - 1465]

… , characterization and use of 1, 3-disulfonic acid imidazolium hydrogen sulfate as an efficient, halogen-free and reusable ionic liquid catalyst for the trimethylsilyl …

[Shirini, Farhad; Khaligh, Nader Ghaffari; Akbari-Dadamahaleh, Somayeh Journal of Molecular Catalysis A: Chemical, 2012 , vol. 365, p. 15 - 23]

Hydride-promoted demethylation of methyl phenyl ethers

[Majetich, George; Zhang, Yong; Wheless, Karen Tetrahedron Letters, 1994 , vol. 35, # 47 p. 8727 - 8730]

One-pot hydrothermal synthesis of mesoporous V-SBA-16 with a function of the pH of the initial gel and its improved catalytic performance for benzene hydroxylation

[Zhao, Lina; Dong, Yongli; Zhan, Xinlin; Cheng, Yi; Zhu, Yujun; Yuan, Fulong; Fu, Honggang Catalysis Letters, 2012 , vol. 142, # 5 p. 619 - 626]

Ligand-and base-free synthesis of phenols by rapid oxidation of arylboronic acids using iron (III) oxide

[Sawant, Sanghapal D.; Hudwekar, Abhinandan D.; Aravinda Kumar; Venkateswarlu, Vunnam; Singh, Parvinder Pal; Vishwakarma, Ram A. Tetrahedron Letters, 2014 , vol. 55, # 4 p. 811 - 814]

More Articles...