Tetrahedron letters

One-step deoxygenation of alcohols into alkanes by a'double electrolysis' in the presence of a phosphine

H Maeda, T Maki, K Eguchi, T Koide, H Ohmori

Index: Maeda, Hatsuo; Maki, Toshihide; Eguchi, Kaoru; Koide, Takashi; Ohmori, Hidenobu Tetrahedron Letters, 1994 , vol. 35, # 24 p. 4129 - 4132

Full Text: HTML

Citation Number: 15

Abstract

Abstract Deoxygenation of primary and secondary alcohols was effectively achieved in one- step by constant current electrolysis of a mixture of a phosphine, an alcohol, and Et 4 NBr in CH 3 CN with one compartment cell at room temperature under N 2 atmosphere.

Related Articles:

Versatile Polymer-Bound Rhodium Catalysts. Facile Hydrogenation of Aromatic Compounds in the Liquid Phase

[Okano, Tamon; Tsukiyama, Katsunori; Konishi, Hisatoshi; Kiji, Jitsuo Chemistry Letters, 1982 , p. 603 - 606]

Alkylation of alkenes: Ethylaluminum sesquichloride-mediated hydro-alkyl additions with alkyl chloroformates and di-tert-butylpyrocarbonate

[Journal of the American Chemical Society, , vol. 126, # 33 p. 10319 - 10330]

Stereoselective hydrogenation of tert-butylphenols over charcoal-supported rhodium catalyst in supercritical carbon dioxide solvent

[Journal of Catalysis, , vol. 252, # 1 p. 57 - 68]

Alkylation of alkenes: Ethylaluminum sesquichloride-mediated hydro-alkyl additions with alkyl chloroformates and di-tert-butylpyrocarbonate

[Journal of the American Chemical Society, , vol. 126, # 33 p. 10319 - 10330]

Activation of reducing agents. sodium hydride containing complex reducing agents 26: New efficient desulfurizing nickel containing reagents

[Becker, S.; Fort, Y.; Vanderesse, R.; Caubere, P. Tetrahedron Letters, 1988 , vol. 29, # 24 p. 2963 - 2966]

More Articles...