Organic letters

Microwave-accelerated iridium-catalyzed borylation of aromatic C− H bonds

P Harrisson, J Morris, TB Marder, PG Steel

Index: Harrisson, Peter; Morris, James; Marder, Todd B.; Steel, Patrick G. Organic Letters, 2009 , vol. 11, # 16 p. 3586 - 3589

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Citation Number: 71

Abstract

Microwave heating accelerates the Ir-catalyzed C− H borylation of aromatic substrates when compared with reactions carried out at the same temperature under standard heating conditions. Application to a one-pot single solvent process for tandem C− H borylation/Suzuki− Miyaura cross-coupling sequences using microwave-accelerated reactions gives fast and efficient access to a wide range of biaryl and heterobiaryl ...