Small-Ring Compounds. XXXV. Studies of Rearrangements in the Nitrous Acid Deaminations of Methyl-substituted Cyclobutyl-, Cyclopropylcarbinyl-and …

MS Silver, MC Caserio, HE Rice…

Index: Silver,M.S. et al. Journal of the American Chemical Society, 1961 , vol. 83, p. 3671 - 3678

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Citation Number: 29

Abstract

The compositions of the alcohol mixtures formed in nitrous acid deaminations of cyclopropylmethylcarbinylamine,(2-methylcyclopropyl)-carbinylamine, 2- methylcyclobutylamine, 3-methylcyclobutylamine, crotylcarbinylamine and allylmethylcarbinylamine have been determined. These results and the behavior of the corresponding alcohols under isomerization conditions in strongly acidic media may be ...