Fremy's salt (potassium nitrosodisulphonate): a nitrosating reagent for amines
L Castedo, R Riguera, MP Vázquez
Index: Castedo, Luis; Riguera, Ricardo; Vazquez, M. Pilar Journal of the Chemical Society, Chemical Communications, 1983 , # 6 p. 301 - 302
Full Text: HTML
Citation Number: 29
Abstract
Treatment of secondary and tertiary amines with Fremy's salt in aqueous sodium carbonate or pyridine solution gives moderate yields of the corresponding N-nitrosoamines. ... The ability of Fremy's salt (1) (potassium nitrosodisulphonate) to act as a one electron oxidant towards amines has recently been rep0rted.I Unexpectedly, N-nitrosopiperidine was ob- tained as a secondary reaction product. This, coupled with the significance of nitrosoamines as carcinogenic ...
Related Articles:
[Iranpoor, Nasser; Firouzabadi, Habib; Pourali, Ali Reza Synthetic Communications, 2005 , vol. 35, # 11 p. 1517 - 1526]
Reactions of trifluoroamine oxide: a route to acyclic and cyclic fluoroamines and N-nitrosoamines
[Journal of the American Chemical Society, , vol. 112, # 6 p. 2383 - 2386]
[Iranpoor, Nasser; Firouzabadi, Habib; Pourali, Ali-Reza Synthesis, 2003 , # 10 p. 1591 - 1597]
Facile formation of N-nitrosamines from bromonitromethane and secondary amines
[Challis, Brian C.; Yousaf, Taher I. Journal of the Chemical Society, Chemical Communications, 1990 , # 22 p. 1598 - 1599]
Reaction of methylmagnesium iodide with dibutylcyanamide and dibutylnitrosamine
[Polivin, Yu. N.; Karakhanov, R. A.; Kelarev, V. I.; Sheveleva, T. S.; Ugrak, B. I. Russian Chemical Bulletin, 1993 , vol. 42, # 12 p. 1991 - 1994 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1993 , # 12 p. 2078 - 2081]