The chemical behaviour of cobalt-stabilized carbenes having a trisubstituted silyl or germyl ligand. Stereospecific formation of benzoylsilanes from the reaction of …
G Cerveau, E Colomer, RJP Corriu…
Index: Cerveau, Genevieve; Colomer, Ernesto; Corriu, Robert J.P.; Young, J. Colin Journal of Organometallic Chemistry, 1981 , vol. 205, # 1 p. 31 - 45
Full Text: HTML
Citation Number: 15
Abstract
Abstract We report the chemical behavior of cobalt-stabilized carbenes, R 3 M (CO) 3 CoC (OEt) R′, and their parent anions, R 3 M (CO) 3 CoC (O−) R′, where M= Si or Ge. The anions where M= Si, R′= Ph decompose thermally into the corresponding benzoylsilanes; when the silicon atom is chiral (R 3= MePh-1-Np) optically active R 3 SiCOPh is obtained with complete retention of configuration.
Related Articles:
[Cerveau, G.; Chuit, C.; Corriu, J. P.; Reye, C. Organometallics, 1991 , vol. 10, p. 1510 - 1515]
Microwave-assisted Lewis acid catalysis: Application to the synthesis of alkyl-or arylhalogermanes
[Laurent, Regis; Laporterie, Andre; Dubac, Jacques; Berlan, Jacques Organometallics, 1994 , vol. 13, p. 2493 - 2495]
Iron-catalyzed chlorination of silanes
[Savela, Risto; Zawartka, Wojciech; Leino, Reko Organometallics, 2012 , vol. 31, # 8 p. 3199 - 3206]
GERMANIUM. XVIII. FURTHER ORGANIC COMPOUNDS OF GERMANIUM1
[Journal of the American Chemical Society, , vol. 49, p. 2512 - 2516]
Reactions of organochlorosilanes with chloro-and organogermanes in the presence of aluminum chloride
[Russian Journal of General Chemistry, , vol. 76, # 10 p. 1564 - 1570]