Chlorotrimethylsilane in combination with sodium sulfide as the equivalent of sodium trimethylsilanethiolate in organic reactions
MJ Shiao, LL Lai, WS Ku, PY Lin…
Index: Shiao, Min-Jen; Lai, Long-Li; Ku, Wei-Shan; Lin, Pen-Yuan; Hwu, Jih Ru Journal of Organic Chemistry, 1993 , vol. 58, # 17 p. 4742 - 4744
Full Text: HTML
Citation Number: 43
Abstract
Reagent sodium trimethylsilanethiolate (MeSiSNa) has been used in reduction of aromatic nitro compounds to amines,'conversion of nitriles to thioamides, 2 and removal of a methyl group from metho~ ypyridines.~ This reagent can be generated by reaction of (Me3Si) zS with Na0Me. l Toxicity and stink associated with the expensive (Me3-Si)# reagent, however, limits ita appli~ ability.~?~ Consequently we developed a method for the generation of ...
Related Articles:
Preparation and synthetic utility of phase-transfer catalysts anchored to polystyrene
[Chiles, Margaret Shea; Jackson, Donald D.; Reeves, Perry C. Journal of Organic Chemistry, 1980 , vol. 45, # 14 p. 2915 - 2918]
[Antebi, Shlomo; Alper, Howard Tetrahedron Letters, 1985 , vol. 26, # 22 p. 2609 - 2612]
Highly efficient rhenium-catalyzed deoxygenation of sulfoxides without adding any reducing agent
[Tetrahedron, , vol. 68, # 39 p. 8194 - 8197]
Mild and efficient methods for the conversion of benzylic bromides to benzylic thiols
[Tetrahedron Letters, , vol. 47, # 47 p. 8255 - 8258]
[Tetrahedron Letters, , vol. 26, # 22 p. 2609 - 2612]