Nitroxide chemistry XXII. Oxidation of N, N-bis (trifluoromethyl) hydroxylamine

BL Booth, ED Kosinski, JS Varley

Index: Booth, Brian L.; Kosinski, Edward D.; Varley, John S. Journal of Fluorine Chemistry, 1987 , vol. 37, p. 419 - 428

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Abstract

Abstract A number of cheap oxidising agents have been found to be effective for the conversion of N, N-bis (trifluoromethyl) hydroxylamine into bis (trifluoromethyl) nitroxide. The best of these are cerium (IV) salts either in the solid state or in aqueous acid solution. Efficient, self-indicating processes have been developed using either catalytic amounts of silver (II) picolinate and aqueous potassium persulphate solutions, or electrochemical ...