New aspects of the telluroxide elimination: a facile elimination of sec-alkyl phenyl telluroxide leading to olefins, allylic alcohols, and allylic ethers
S Uemura, S Fukuzawa
Index: Uemura, Sakae; Fukuzawa, Shin-ichi Journal of the American Chemical Society, 1983 , vol. 105, # 9 p. 2748 - 2752
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Citation Number: 47
Abstract
Abstract: The utility of the telluroxide for olefin synthesis, a reaction which previously appeared to be of little value, is described. Treatment of sec-alkylphenyltellurium dibromides, except for the cyclohexyl system, with aqueous NaOH at room temperature affords olefins, allylic alcohols, and/or allylic ethers in high yields presumably via the formation of sec-alkyl phenyl telluroxides and their facile telluroxide elimination. As to the ...
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