Synthesis and optical properties of conjugated N, N-dimethyl and thienyl end-capped 2, 5-(arylethynyl) thiophene oligomer structures

JG Rodrı́guez, A Lafuente, L Rubio, J Esquivias

Index: Rodriguez, J. Gonzalo; Lafuente, Antonio; Rubio, Laura; Esquivias, Jorge Tetrahedron Letters, 2004 , vol. 45, # 38 p. 7061 - 7064

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Citation Number: 13

Abstract

End-capped (N, N-dimethylaminophenyl) and 2′-thienylethynyl 2, 5-thiophene oligomer structures were synthesized by heterocoupling between the terminal acetylenes such as: p- (N, N-dimethylaminophenyl) ethyne (3)[or 1-(p-(N, N-dimethylaminophenyl)-2-p- (ethynylphenyl) ethyne, 4]; p-(β-ethenyl-2′-thienyl) phenylethyne (E-9)[or p-(β-ethynyl-2′- thienyl) phenylethyne, 11], and 2, 5-diiodothiophene, catalyzed by the Cl2Pd (PPh3) 2/CuI ...