Nickel-catalyzed C–H/C–O coupling of azoles with phenol derivatives
K Muto, J Yamaguchi, K Itami
Index: Mochida, Kenji; Kawasumi, Katsuaki; Segawa, Yasutomo; Itami, Kenichiro Journal of the American Chemical Society, 2011 , vol. 133, # 28 p. 10716 - 10719
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Citation Number: 168
Abstract
The first nickel-catalyzed C–H bond arylation of azoles with phenol derivatives is described. The new Ni (cod) 2/dcype catalytic system is active for the coupling of various phenol derivatives such as esters, carbamates, carbonates, sulfamates, triflates, tosylates, and mesylates. With this C–H/C–O biaryl coupling, we synthesized a series of privileged 2- arylazoles, including biologically active alkaloids. Moreover, we demonstrated the utility of ...
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