Room temperature fluorination of aromatic molecules with cesium fluoroxysulphate
S Stavber, M Zupan
Index: Stavber, Stojan; Zupan, Marko Journal of Fluorine Chemistry, 1981 , vol. 17, p. 597 - 600
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Citation Number: 20
Abstract
Abstract Room-temperature fluorination of benzene with cesium fluoroxysulphate in the presence of boron trifluoride as catalyst resulted in the formation of fluorobenzene, while reaction with naphthalene gave 1-fluoro and 2-fluoronaphthalene in the ratio 5: 1, the overall yield being between 38 and 42%. The fluorination of phenanthrene and pyrene should be carried out at higher dilution and needs no catalyst. Phenanthrene gave 9- ...
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