Spin-Carrying Naphthalenediimide and Perylenediimide Derivatives

…, J Yamada, T Kojima, J Nishida, Y Yamashita

Index: Nakatsuji, Shin'ichi; Aoki, Kazunori; Akutsu, Hiroki; Yamada, Jun-Ichi; Kojima, Takahiro; Nishida, Jun-Ichi; Yamashita, Yoshiro Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 9 p. 1079 - 1085

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Citation Number: 5

Abstract

A couple of naphthalenediimide 4 and 5 and series of perylenediimide derivatives 6–9 carrying TEMPO radical were prepared and their redox, FET, and magnetic properties were investigated. The radical compounds 4 and 6–9 were found to show antiferromagnetic interactions obeying the Curie–Weiss model, while the naphthalenediimide derivative 5 exhibited a singlet–triplet magnetic behavior and it could be well understood by the short ...