Journal of the American Chemical Society

ZIRCONIUM. II. ZIRCONIUM OXALATE AND DIPHENYLDINITROGEN ZIRCONIUM

HS Gable

Index: Gable Journal of the American Chemical Society, 1931 , vol. 53, p. 1276

Full Text: HTML

Citation Number: 5

Abstract

Summary A reaction not previously reported has been found to take place between cyanamide and cyanide, resulting in the formation of an intermediate compound which can be hydrolyzed to oxalate. The velocity of this reaction is dependent on hydrogen-ion concentration. Autoclaving calcium cyanide and calcium cyanamide with water produces calcium carbonate, calcium oxalate and a solution of calcium formate. Replacing the water ...