Oxidative displacement and addition reactions of F-tert-butyl hypochlorite with metal chlorides and oxidative additions to several elements

JAM Canich, GL Gard, JM Shreeve

Index: Canich, Joann M.; Gard, Gary L.; Shreeve, Jean'ne M. Inorganic Chemistry, 1984 , vol. 23, p. 441 - 444

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Citation Number: 8

Abstract

Transition-metal and post-transition-metal chlorides underwent oxidative displacement and oxidative addition reactions with F-tert-butyl hypochlorite to form new F-tert-butoxides. Thus, when (CF,) $ OCI was reacted with VOCI,, TiCI4, and Cr02C12, the stable compounds VO [(CF3) 3CO] 3, Ti [(CF3) $0 I4, and CrOl [(CF3) 3CO] z were formed. With Vaska's compound, oxidative addition occurred at iridium but the phenyl groups of P (C6HS) 3 were also ...