Palladium-catalyzed and copper-mediated cross-coupling reaction of aryl-or alkenylboronic acids with acid chlorides under neutral conditions: efficient synthetic …
…, Y Inoue, M Fujisawa, M Iwasaki, K Takagi, Y Nishihara
Index: Ogawa, Daisuke; Hyodo, Keita; Suetsugu, Masato; Li, Jing; Inoue, Yoshiaki; Fujisawa, Mamoru; Iwasaki, Masayuki; Takagi, Kentaro; Nishihara, Yasushi Tetrahedron, 2013 , vol. 69, # 12 p. 2565 - 2571
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Citation Number: 15
Abstract
Palladium-catalyzed cross-coupling reaction of aryl-or alkenylboronic acids with acid chlorides in the presence of copper (I) thiophene-2-carboxylate (CuTC) as an activator in diethyl ether at room temperature under strictly non-basic conditions affords the diaryl ketones or chalcones in moderate to excellent yields. A wide range of substrates bearing an electron-donating or an electron-withdrawing substituent on the aromatic ring are ...
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