Nucleophilic aromatic substitution of Cr (CO) 3 complexed dihaloarenes with thiolates

A Alemagna, P Cremonesi, P Del Buttero…

Index: Alemagna, Andreina; Cremonesi, Paolo; Buttero, Paola Del; Licandro, Emanuela; Maiorana, Stefano Journal of Organic Chemistry, 1983 , vol. 48, # 18 p. 3114 - 3116

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Citation Number: 37

Abstract

Method B. Compound 10 (6.9 mg, 0.05" 01) was mixed with silver acetate (47 mg, 0.25" 01) and dissolved in pyridine-water (9: 1, v/v, 2 mL). The solution was immediately evaporated in vacuo and the residue was again dissolved in pyridinewater (2: 1, v/v, 0.25 mL). The resulting solution was stirred vigorously at room temperature for 24 h. Then the mixture was diluted with pyridine-water (2: 1, v/v, 5 mL) and cooled to 0" C. To the solution was ...