Induced halogenation of alkyl cyclohexenyl ketones involving metal halides, hydrohalogenic acids, and hydrogen peroxide
OA Sadygov, KM Alimardanov
Index: Sadygov; Alimardanov Russian Journal of Organic Chemistry, 2009 , vol. 45, # 2 p. 166 - 172
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Citation Number: 1
Abstract
Abstract The induced halogenation and hydroxyhalogenation of alkyl cyclohexenyl ketones in a system [MHlg+ HHlg or HHlg]-H 2 O 2 or in NaOCl was performed and optimum reaction conditions were established. Under mild conditions the electrophilic addition of the halogen or the acid occurred at the multiple bond of the ring with the formation of the corresponding dihalo or hydroxyhalo derivatives of cycloaliphatic ketones. From the compounds obtained ...
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