Phosphine sulfides as an anchor unit for single molecule junctions

…, Y Tsuji, A Staykov, K Yoshizawa, S Yamaguchi

Index: Fukazawa, Aiko; Kiguchi, Manabu; Tange, Satoshi; Ichihashi, Yasunori; Zhao, Qiang; Takahashi, Takuya; Konishi, Tatsuya; Murakoshi, Kei; Tsuji, Yuta; Staykov, Aleksandar; Yoshizawa, Kazunari; Yamaguchi, Shigehiro Chemistry Letters, 2011 , vol. 40, # 2 p. 174 - 176

Full Text: HTML

Citation Number: 19

Abstract

Phenylene and biphenyl compounds with dibenzophosphole sulfide (DBPS) as an anchoring group for single molecule junctions were synthesized. The conductance measurements revealed that the phosphine sulfide indeed acts as an anchoring group for Au electrodes. Theoretical calculations including metal electrodes demonstrated that the LUMO level of the DBPS-terminated biphenyl is close to the Au Fermi level, leading to the ...