(Sensitized) photolysis of diazonium salts as a mild general method for the generation of aryl cations. Chemoselectivity of the singlet and triplet 4-substituted phenyl …
S Milanesi, M Fagnoni, A Albini
Index: Butler, Richard N.; O'Shea, Paul D.; Shelly, Declan P. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 1039 - 1042
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Citation Number: 55
Abstract
... The Journal of Organic ... been formed by the palladium-mediated reactions with aryl boronic acids 7 (path c) or with olefins in the Heck synthesis 8 (path d). ... occupancy of that orbital and the charge delocalized on the aromatic ring and on the substituents in the o- or p-positions. ...
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