Bioorganic & medicinal chemistry

Deoxynucleic guanidine: synthesis and incorporation of purine nucleosides into positively charged DNG oligonucleotides

H Challa, TC Bruice

Index: Challa, Hemavathi; Bruice, Thomas C. Bioorganic and Medicinal Chemistry, 2004 , vol. 12, # 6 p. 1475 - 1481

Full Text: HTML

Citation Number: 15

Abstract

The synthesis of purine nucleosides capable of making the guanidinium linkage is described for the first time starting from the corresponding 2′-deoxynucleosides. The positively charged mixed base DNG oligomer containing guanine was synthesized on solid- phase using CPG as support from 3′ to 5′ direction using the precursor building block nucleosides.

Related Articles:

Microwave Assisted High Yielding Preparation of N-Protected 2′-Deoxyribonucleosides Useful for Oligonucleotide Synthesis

[Rao; Kumar; Chauhan; Garg; Gupta Nucleosides, Nucleotides and Nucleic Acids, 2002 , vol. 21, # 4-5 p. 393 - 400]

A new strategy for the protection of deoxyguanosine during oligonucleotide synthesis

[Gaffney, B. L.; Jones, R. A. Tetrahedron Letters, 1982 , vol. 23, # 22 p. 2257 - 2260]

Dimethoxybenzoin carbonates: Photochemically-removable alcohol protecting groups suitable for phosphoramidite-based DNA synthesis

[Pirrung, Michael C.; Bradley, Jean-Claude Journal of Organic Chemistry, 1995 , vol. 60, # 5 p. 1116 - 1117]

Design and synthesis of bis-carbamate analogs of cyclic bis-(3′-5′)-diguanylic acid (c-di-GMP) and the acyclic dimer PGPG

[Kline, Toni; Jackson, Stona R.; Deng, Wei; Verlinde, Christophe L. M. J.; Miller, Samuel I. Nucleosides, Nucleotides and Nucleic Acids, 2008 , vol. 27, # 12 p. 1282 - 1300]

A new strategy for the protection of deoxyguanosine during oligonucleotide synthesis

[Tetrahedron Letters, , vol. 23, # 22 p. 2257 - 2260]

More Articles...