Formation of Quaternary Carbon Centers by Highly Regioselective Hydroformylation with Catalytic Amounts of a Reversibly Bound Directing Group
Y Ueki, H Ito, I Usui, B Breit
Index: Ueki, Yusuke; Ito, Hideto; Usui, Ippei; Breit, Bernhard Chemistry - A European Journal, 2011 , vol. 17, # 31 p. 8555 - 8558
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Citation Number: 11
Abstract
With nine million tons of oxoproducts produced worldwide per year, the hydroformylation of olefins is the largest volume application of homogeneous catalysis in industry.[1, 2] Thus, in the presence of a suitable transition-metal catalyst, CO and hydrogen are added across the carbon–carbon double bond of an alkene to give the homologated aldehydes in complete accord with the criteria of atom economy.[3] The aldehydes formed are useful functional ...
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