Tetrahedron

Convenient synthesis of 5-aryl (alkyl) sulfanyl-1, 10-phenanthrolines from 5, 6-epoxy-5, 6-dihydro-1, 10-phenanthroline, and their activity towards fungal β-d- …

IA Dotsenko, M Curtis, NM Samoshina, VV Samoshin

Index: Dotsenko, Irina A.; Curtis, Matthew; Samoshina, Nataliya M.; Samoshin, Vyacheslav V. Tetrahedron, 2011 , vol. 67, # 39 p. 7470 - 7478

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Citation Number: 12

Abstract

A broad series of novel 5-aryl (alkyl) sulfanyl-1, 10-phenanthrolines has been prepared by a new simple procedure: a treatment of the commercially available 5, 6-epoxy-5, 6-dihydro-1, 10-phenanthroline with various thiols in the presence of a base. Other functional groups attached to the thiol allow a use of the products as building blocks in synthesis of versatile ligands and in functionalization of surfaces. The synthesized phenanthrolines showed a ...

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