Helvetica Chimica Acta

Über eine neuartige Basen??katalysierte Umlagerung der Nitroso??Gruppe

HU Daeniker

Index: Daeniker,H.U. Helvetica Chimica Acta, 1964 , vol. 47, p. 33 - 46

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Citation Number: 11

Abstract

Abstract By treatment with bases in methanolic solution N-substituted N-nitroso-amino- acetonitriles (I) undergo an internal rearrangement of the nitroso group to yield α-isonitroso- aminoacetonitriles (II). The structures of the rearrangement products are proved by their physico-chemical properties, by chemical degradation to known products, and by transformation into a number of derivatives. Similar compounds in which the nitrile group ...