Colloid-catalysed arene hydrogenation in aqueous/supercritical fluid biphasic mediaElectronic supplementary information (ESI) available: experimental details, …
RJ Bonilla, BR James, PG Jessop
Index: Bonilla, R. Jason; James, Brian R.; Jessop, Philip G. Chemical Communications, 2000 , # 11 p. 941 - 942
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Citation Number: 77
Abstract
Hydrogenation of arenes, including the lignin model compound 2-methoxy-4-propylphenol, has been effected using a Rh colloid in biphasic aqueous/supercritical ethane reaction media; this is the first successful example of an unsupported colloid-catalysed hydrogenation of a substrate in a supercritical fluid; the same reaction does not proceed in aqueous/supercritical carbon dioxide or ionic liquid/supercritical fluid media.
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