Aerobic reduction of olefins by in situ generation of diimide with synthetic flavin catalysts
Y Imada, H Iida, T Kitagawa…
Index: Imada, Yasushi; Iida, Hiroki; Kitagawa, Takahiro; Naota, Takeshi Chemistry - A European Journal, 2011 , vol. 17, # 21 p. 5908 - 5920
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Citation Number: 41
Abstract
Abstract A versatile reducing agent, diimide, can be generated efficiently by the aerobic oxidation of hydrazine with neutral and cationic synthetic flavin catalysts 1 and 2. This technique provides a convenient and safe method for the aerobic reduction of olefins, which proceeds with 1 equiv of hydrazine under an atmosphere of O 2 or air. The synthetic advantage over the conventional gas-based method has been illustrated through high ...
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