Amination of arenes with N, N-dimethyl-2-imidazolidinone o-methoxyacetyloxime
N Baldovini, M Kitamura, K Narasaka
Index: Baldovini, Nicolas; Kitamura, Mitsuru; Narasaka, Koichi Chemistry Letters, 2003 , vol. 32, # 6 p. 548 - 549
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Citation Number: 4
Abstract
Direct amination of arenes has been considered as a straightforward method for the synthesis of aniline derivatives.1 In the course of our study on the utilization of oxime deriva- tives as electrophilic amination reagents,2 it was found that in the presence of Lewis acids, cyclic O-sulfonyl- or O-acyloximes could be used for the amination of nucleophilic arenes. This process involves the formation of imines from the oximes and arenes and the successive hydrolysis leading to ...
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