Unusual selective. alpha.-fission of indium-sec-alkyl bonds in solution

R Nomura, S Miyazaki, H Matsuda

Index: Nomura, Ryoki; Miyazaki, Shin-Ichiro; Matsuda, Haruo Organometallics, 1992 , vol. 11, p. 2 - 4

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Abstract

Scheme I Me C ti 0~dCo)iz #?-f(. \ I +HC,R ,OS-OS, \ I I/ *CO _t ... \I/" 34'c '\l/&fR os' \H 60.C H, ,c=c'H ,R 'I\ (MeO),SI SI(OMe), /OS( I SI(OMe), la 2a, R BU~' ... (8) Adams, RD; Cortopassi, J. E.; Pompeo, M. P. Inorg. Chem. 1991, 30, 2960. (9) Compound la was prepared by a procedure analogous to that used for the preparation of lb.* Analytical data for la: IR (YCO, cm-'; in hexane) 2104 (m), 2066 (vs), 2042 (vs), 2022 (vs), 2009 (s), 2001 (vs), 1989 (vs), 1977 ...