Heavy atom isotope effect studies of elimination reaction mechanisms. 1. A kinetic and carbon-14 kinetic isotope effect study of the base-promoted …
T Hasan, LB Sims, A Fry
Index: Hasan, Tayyaba; Sims, Leslie B.; Fry, Arthur Journal of the American Chemical Society, 1983 , vol. 105, # 12 p. 3967 - 3975
Full Text: HTML
Citation Number: 20
Abstract
Abstract: Upon treatment with the solvent conjugate base, the primary reaction of substituted 1-phenylethyl chlorides is elimination to substituted styrenes in t-BuOH-10% v/v Me2S0 at 60 OC and in bis (Zhydroxyethy1) ether-10% v/v Me2S0 at 45 OC. Kinetic studies using eight substituted chlorides show that these reactions are strongly accelerated by both electron-donating and electron-withdrawing substituents, probably indicating a fairly ...
Related Articles:
Silica gel promotes reductions of aldehydes and ketones by N-heterocyclic carbene boranes
[Kouhkan, Mehri; Zeynizadeh, Behzad Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 10 p. 2961 - 2966]
QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
[Li, Jia; Wang, Chao; Xue, Dong; Wei, Yawen; Xiao, Jianliang Green Chemistry, 2013 , vol. 15, # 10 p. 2685 - 2689]
Cerium (III) bromate as a new reagent in oxidation of organic compounds
[Shaabani, Ahmad; Lee, Donald G. Synthetic Communications, 2003 , vol. 33, # 11 p. 1845 - 1854]
[Yu; Zeng; Sun; Deng; Dong; Chen; Wang; Pei Journal of Organometallic Chemistry, 2007 , vol. 692, # 11 p. 2306 - 2313]
[Angewandte Chemie - International Edition, , vol. 48, # 3 p. 539 - 542]