α, β??Unsaturated Aldehydes as Substrates for Asymmetric C C Bond Forming Reactions with Thiamin Diphosphate (ThDP)??Dependent Enzymes

A Cosp, C Dresen, M Pohl, L Walter…

Index: Cosp, Anabel; Dresen, Carola; Pohl, Martina; Walter, Lydia; Roehr, Caroline; Mueller, Michael Advanced Synthesis and Catalysis, 2008 , vol. 350, # 5 p. 759 - 771

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Citation Number: 32

Abstract

Abstract The enzymes benzaldehyde lyase (BAL) from Pseudomonas fluorescens, benzoylformate decarboxylase (BFD) from Pseudomonas putida and pyruvate decarboxylase (PDC) from Saccharomyces cerevisiae provide different C [BOND] C bond forming possibilities of α, β-unsaturated aldehydes with aliphatic and aromatic aldehydes. Structure elucidation and determination of the absolute configuration of the products, ...

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