A Study of 1, 2-Benzyl and 1, 3-Phenyl Radical Migrations
LH Slaugh, EF Magoon, VP Guinn
Index: Slaugh,L.H. et al. Journal of Organic Chemistry, 1963 , vol. 28, p. 2643 - 2646
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Abstract
These results are The 3-phenylpropyl-l-Cl4 radical similarly generated does not or by the" Kharasch reaction" of l, l-dibenzyl-2-chloroethane, does not rearrange via a 1, 2-benzyl shift. dence suggests that for free radicals the migratory aptitude is in the order phenyl> benzyl. compared with those reported for carbanions. rearrange to the 1-phenylpropyl-l-C14 radical via a 1, 3-phenyl shift.
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