Decomposition of 4, 4-dimethylpent-1-ene in the presence of oxygen between 400 and 500 C: oxidation chemistry of allyl radicals
ZH Lodhi, RW Walker
Index: Lodhi, Zulfiqar H.; Walker, Raymond W. Journal of the Chemical Society, Faraday Transactions, 1991 , vol. 87, # 5 p. 681 - 689
Full Text: HTML
Citation Number: 32
Abstract
The decomposition of 4, 4-dimethylpent-1-ene (DMP) in the presence of O2 has been used as a source of allyl radicals over the temperature range 400–500° C. The reaction has been studied in both KCl-coated (peroxy species destroyed at the surface) and aged boric-acid- coated vessels (peroxy species preserved), and the basic mechanism shown to be: DMP→ t- butyl+[graphic omitted](1), t-butyl+ O2→ i-C4H8+ HO2 (2). Previous studies have shown ...
Related Articles:
[Adam, Waldemar; Cadiz, Carlos; Mazenod, Francois Tetrahedron Letters, 1981 , vol. 22, # 13 p. 1203 - 1206]
[Hodgson, David M.; Le Strat, Frederic; Avery, Thomas D.; Donohue, Andrew C.; Brueckl, Tobias Journal of Organic Chemistry, 2004 , vol. 69, # 25 p. 8796 - 8803]
[Levanova, Ekaterina P.; Grabelnykh, Valentina A.; Elaev, Alexander V.; Albanov, Alexander I.; Klyba, Lyudmila V.; Russavskaya, Natalia V.; Tarasova, Olga A.; Rozentsveig, Igor B.; Korchevin, Nikolai A. Journal of Sulfur Chemistry, 2012 , vol. 33, # 5 p. 505 - 511,7]
[Grigg, Ronald; MacLachlan, William S; MacPherson, David T; Sridharan, Visuvanathar; Suganthan, Selvaratnam Tetrahedron, 2001 , vol. 57, # 52 p. 10335 - 10345]
[Grigg, Ronald; MacLachlan, William S; MacPherson, David T; Sridharan, Visuvanathar; Suganthan, Selvaratnam Tetrahedron, 2001 , vol. 57, # 52 p. 10335 - 10345]