Selective lithiation of 1-bromo-2 [(trimethylstannyl) methyl] benzene: synthesis of 1-bromo-2-(lithiomethyl) benzene, 1-lithio-2-[(trimethylstannyl) methyl] benzene, and. …

HJR De Boer, OS Akkerman, F Bickelhaupt

Index: Boer, Henricus J. R. de; Akkerman, Otto S.; Bickelhaupt, Fridrich Organometallics, 1990 , vol. 9, p. 2898 - 2903

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Abstract

Results Reactions of 1 with n-BuLi. A series of reactions between 1 and n-BuLi was conducted under various conditions (Table I and Scheme I). In a typical experiment, 1 was added to n-BuLi in diethyl ether (with some n-hexane, see Experimental Section) at the indicated tem-(1)(a) Schollkopf, U. In Houben Weyl, Methoden der Organischen Chemie; Muller, E., Ed.; G. Thieme Verlag: Stuttgart, FRG, 1970; Vol. 13/1, p 128.(b) Wardell, JL In ...