Trichlorosilane-tertiary amine combinations as reducing agents for polyhalo compounds. Potential analogies with phosphorus chemistry

RA Benkeser, WE Smith

Index: Benkeser,R.A.; Smith,W.E. Journal of the American Chemical Society, 1968 , vol. 90, p. 5307 - 5309

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Citation Number: 42

Abstract

at-5", while 1-methylcyclopropyl nitrite and nitrite esters of other cyclopropanols without 2 substituents are stable until near room temperature, Nitrite esters of 2, 2, 3, 3- tetramethylcyclopropanols8 are particularly unstable, the parent ester decomposing at-55" and the 1-methoxy derivative at-80". Nitrite esters of ordinary alcohols undergo thermolysis only at elevated temperatures (150-200"), and the rates of their decomposition are not ...